By Moody C.J.
This quantity features a diversity of issues corresponding to the activation and manipulation of pyrroles, the synthesis of annelated pyrroles utilizing acylation reactions and the synthesis of kainoids, a family members of hugely biologically lively nitrogen heterocycles.
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Extra resources for Advances in Nitrogen Heterocycles, Volume 3
Harman, W. J. Am. Chem. Soc. 1994,116, 7931. (b) Hodges, L. ; Spera, M. U; Moody, M. ; Harman, W. D. J. Am. Chem. Soc. 1996, 118, 7117. 14. ; Koontz, J. ; Hodges, L. ; Nilsson, K. ; Neely, L. ; Myers, W. ; Harman, W. D. J. Am. Chem. Soc. 1995, 117, 3405. 15. The pentaammineosmium(II) metal center also binds in a dihapto fashion to several other classes of aromatic molecules, including benzenes, naphthalenes, phenols, anisoles, anilines, furans, and thiophenes, activating them toward further functionalization.
EDSTROM I. INTRODUCTION The efficient and regioselective synthesis of substituted pyrrole tings continues to be an important goal in organic synthesis. Much of the motivation derives from the diverse array of naturally occurring compounds that contain either pyrrole rings or pyrrole tings embedded within their structural frameworks. Examples that are of particular relevance to this chapter include pyrrolo[2,3-d]pyrimidines, pyrrolo[ 1,2-c]pyridines, pyrido[3,4-b]pyrrolozidines, 3,4-disubstituted indoles, indole-4,7-quinones, and pyrrolo[ 1,2-a]indoles, as revealed below.
Sikorski, J. A. J. Org. Chem. 1990, 55, 4735. (c) Gallagher, P. ; Palmer, J. ; Morgan, S. E. J. Chem. Soc. Perkin Trans. 11990, 3212. ;1Leusen, A. M. J. Org. Chem. 1992, 57, 2245. For a review of 13-substituted pyrrole syntheses, see: Anderson, H. ; Loader, C. E. Synthesis 1985, 353, and references therein. 3. Bray, B. ; Mathies, P. ; Solas, D. ; Tidwell, T. ; Artis, D. ; Muchowski, J. M. J Org. Chem. 1990, 55, 6317, and references therein. 4. ; Trudell, M. L. Chem. Rev. 1996, 96, 1179, and references therein.
Advances in Nitrogen Heterocycles, Volume 3 by Moody C.J.